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Tuesday 07th February 2012 12:23
 
  

Below is a series of principle synthetic reactions that have been broken down mechanistically with some additional practical notes on optimising yields. I have also taken a deeper look at some pharmaceutically relevant heterocyclic materials, namely functionalised indoles, a moiety which featured heavily in my PhD.

| General

Aldol Reaction
>  
Knoevenagel Condensation

Michael Addition

Wittig Reaction
>  
Horner-Wadsworth-Emmons Modification
>   Schlosser Modification

Esterification
>   Yamaguchi Esterification



| Indolisation

Fischer Indole Synthesis

Madelung Indole Synthesis

Larock Indole Synthesis

Leimgruber-Batcho Indole Synthesis

Bischler-Möhlau Indole Synthesis

Bartoli Indole Synthesis


| Halogenation

Free Radical Halogenation

Electrophilic Halogenation (via acid/base)


| Cross Coupling Reactions

Mizoroki-Heck Reaction

Sonogashira Reaction

Stille Reaction

Suzuki-Miyaura Reaction

 
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